Arenechromium complexed diastereomeric aminophosphine-phosphinite ligands derived from tetrahydroisoquinoline have been synthesised and examined as chiral auxiliaries in the hydrogenation of functionalised ketones. A cyclopentyl-substituted anti-stereoisomer is providing the highest enantioselectivi
✦ LIBER ✦
New chiral chelating phosphine complexes containing tricarbonyl(η6-arene) chromium for highly enantioselective allylic alkylation
✍ Scribed by Yoshinori Hayashi; Hiroshi Sakai; Naotake Kaneta; Motokazu Uemura
- Book ID
- 103232895
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 646 KB
- Volume
- 503
- Category
- Article
- ISSN
- 0022-328X
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