𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chiral tricarbonyl(η6-arene)chromium complexed diphosphanes. Highly enantioselective rhodium-mediated hydrogenation of ketones

✍ Scribed by Corinne Pasquier; Lydie Pélinski; Jacques Brocard; André Mortreux; Francine Agbossou-Niedercorn

Book ID
104230396
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
75 KB
Volume
42
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Arenechromium complexed diastereomeric aminophosphine-phosphinite ligands derived from tetrahydroisoquinoline have been synthesised and examined as chiral auxiliaries in the hydrogenation of functionalised ketones. A cyclopentyl-substituted anti-stereoisomer is providing the highest enantioselectivities (up to >99% ee).

📜 SIMILAR VOLUMES

ChemInform Abstract: Chiral Tricarbonyl(
ChemInform Abstract: Chiral Tricarbonyl(η6-arene)chromium Complexed Diphosphanes. Highly Enantioselective Rhodium-Mediated Hydrogenation of Ketones.
✍ Corinne Pasquier; Lydie Pelinski; Jacques Brocard; Andre Mortreux; Francine Agbo 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v