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New chiral bicyclic phosphoramides derived from (L)-glutamic acid

โœ Scribed by Peyronel, Jean Francois; Samuel, Odile; Fiaud, Jean Claude


Book ID
127314726
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
871 KB
Volume
52
Category
Article
ISSN
0022-3263

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A stereo-and enantio-specific synthesis of the natural1 occurring cis-%hydroxy-(L)-pipecolic acid (3) is described, starting from Z-(L -glutamic the key step involves c chsation of a Y, to trans-%hydroxy-(L -pipecolic acl 3 3 rotected chlorohydrin, and also gives access acid, .