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New Catalytic Approaches towards the Enantioselective Halogenation of Alkenes

✍ Scribed by Dr. Ulrich Hennecke

Book ID
112006504
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
738 KB
Volume
7
Category
Article
ISSN
1861-4728

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The electrophilic additions of hydroperoxyl HO , alkylperoxyl RO , 2 2 and halogenated alkylperoxyl radicals to ethylene were studied using the AM1 and PM3 semiempirical MO methods at the SCFrUHF level. Reactantlike transition states were Ε½ U . predicted for the title additions. The AM1 activation e

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