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New base-labile amino-protective groups for peptide synthesis

โœ Scribed by C.G.J. Verhart; G.I. Tesser

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
636 KB
Volume
107
Category
Article
ISSN
0165-0513

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## Abstract A new baseโ€labile anchoring group, derived from 9โ€(hydroxymethyl)fluoreneโ€4โ€carboxylic acid (HO~2~CFmoH or HOFmCO~2~H; 7), for polymerโ€supported peptide synthesis os described. The synthesis of 7 starting from 2,2โ€ฒโ€biphenyldicarboxylic acid (**1**) proceeds in an overall yield of 53%. T

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Despite continuing research,' the groups available for protection of amino and carboxyl functions of peptides fail to meet the most stringent demands of synthesis. Particularly needed