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New aspects of the solvent mode in the photoinduced electron transfer in polar solution

โœ Scribed by Toshiaki Kakitani

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
247 KB
Volume
40-41
Category
Article
ISSN
0022-2313

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๐Ÿ“œ SIMILAR VOLUMES

Effect of the dielectric saturation on t
Effect of the dielectric saturation on the rates of electron transfer in polar solvents
โœ M. Tachiya ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 463 KB

Recently Kakitani and Mataga claimed that the free energy dependence of electron transfer rates in polar solvents could be explained by taking into account the dielectric saturation effect of polar solvents. It is shown that the basic assumption of their model is incorrect. The correct treatment of

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โœ N. Sutin ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 428 KB

Some recent studies of inner-sphere and outer-sphere electron-transfer reactions in solution are described. Various indirect criteria for determining the mechanisms of electron-transfer re actions and the question of ligand bridging at electrodes are discussed.

Monte Carlo simulation study on energy-g
Monte Carlo simulation study on energy-gap dependence of electron-transfer reactions in polar solution: Effect of electronic polarizability of solvent
โœ Yoshitaka Enomoto; Toshiaki Kakitani; Akira Yoshimori; Yasuyo Hatano ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 444 KB

We conducted Monte Carlo simulations of polar solutions by explicitly treating the effect of electronic polarizability of solvent molecules. Based on these data, we calculated the energy-gap dependence of electron-transfer rates. It was found that a considerable asymmetry of the energy-gap dependenc