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New Aspects in the Stereoselective Ethynylation of β-C-Glycoside Aldehydes. Application to the Synthesis of an Ambruticin Fragment.

✍ Scribed by Veronique Michelet; Kouacou Adiey; Suzelle Tanier; Gilles Dujardin; Jean-Pierre Genet


Book ID
101955544
Publisher
John Wiley and Sons
Year
2003
Weight
242 KB
Volume
34
Category
Article
ISSN
0931-7597

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✍ Qianyong Xu; Hui Wang; Xinfu Pan; Albert S.C Chan; Teng-kuei Yang 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 68 KB

The C 2 -symmetrical bis-b-amino alcohols 1-6 were prepared and especially attention is focused on bridges, which link the two b-amino alcohol units. These ligands have been applied as chiral catalysts in the asymmetric addition of diethylzinc to aldehydes. sec-Alcohols have been obtained in good yi