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New applications of the wittig reaction to the preparation of strained bridgehead olefins

✍ Scribed by William G. Dauben; Jeffrey D. Robbins

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
204 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the past few years there has been a rapid growth of interest in the n preparation of strained bridgehead olefins'. Until recently the reported synthetic approaches all involved a separate construction of the ring system prior to introduction of the double bond. In 1973, however, a facile synthesis for such olefins was reported3 from this laboratory which utilized the intramolecular Wittig reaction4 and therefore effected ring closure and double bond formation in a single xeaction step.

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