𝔖 Bobbio Scriptorium
✦   LIBER   ✦

New and unexpected developments of the carbanion-mediated sulfonate (sulfonamide) intramolecular cyclization reaction (CSIC reaction)

✍ Scribed by JoséL. Marco; S.T. Ingate; Pilar Manzano

Book ID
104259268
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
143 KB
Volume
39
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The Carbanion-mediated Sulfonate (Sulfonamide) Intramolecular Cyclization reaction (CSIC reaction) on conveniently functionalized cyanoalkylsulfonates and eyanoalkylsulfonamides derived from aldehydes is possible and gives the new heterocyclic ring systems 5-alkyl-5H-4-amino-l,2-oxathiole-2,2dioxide and 5-alkyl-5H-4-amino-3-cyano-2,3-dilaydroisothiazole-1,1-dioxide in good yield.

📜 SIMILAR VOLUMES

ChemInform Abstract: The CSIC [Carbanion
ChemInform Abstract: The CSIC [Carbanion Mediated Sulfonate (Sulfonamido) Intramolecular Cyclization] Reaction: Scope and Limitations.
✍ Jose L. Marco; S. T. Ingate; P. M. Chinchon 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

The CSIC [Carbanion Mediated Sulfonate (Sulfonamido) Intramolecular Cyclization] Reaction: Scope and Limitations. -Sulfonate and sulfonamido intermediates of type (V), (X), (XII), and (XIV) derived from cyclopropyl methyl ketone and cyclic azaketones are found to successfully undergo the CSIC react