New and Efficient Synthesis of Azabicyclo[4.4.0]alkane Amino Acids by Rh-Catalyzed Cyclohydrocarbonylation.
✍ Scribed by Nobuhiro Mizutani; Wen-Hua Chiou; Iwao Ojima
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 197 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## COMNIUNtCATIONS sities were registered to 25 = 5 0 ' . Of 8639 reflections, 5330 were independent (R,,, = 0.0406). An absorption correction based on $ scans was applied. The structure was solved with the heavy atom method and refined against F2 (SHELXL-93). Methyl H atoms were included by using
## Abstract Highly regio‐ and enantioselective Ir‐catalyzed allylic amination reactions of N‐tosyl propynylamines with allylic carbonates result in the formation of N‐tosyl allylpropynylamines.
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