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ChemInform Abstract: Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptenes and 3-Azabicyclo[3.2.0]heptenes by Ir-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization.

✍ Scribed by Ji-Bao Xia; Wen-Bo Liu; Tian-Min Wang; Shu-Li You

Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201043038

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✦ Synopsis

Abstract

Highly regio‐ and enantioselective Ir‐catalyzed allylic amination reactions of N‐tosyl propynylamines with allylic carbonates result in the formation of N‐tosyl allylpropynylamines.

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