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New and efficient synthesis of 5′-amino-5′-(S)-methyl-2′,5′-dideoxynucleosides

✍ Scribed by Pierre M.J. Jung; Renaud Beaudegnies; Alain De Mesmaeker; Sebastian Wendeborn

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
233 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

A short, efficient synthesis of 5%-amino-5%-(S)-methyl-2%,5%-dideoxynucleosides 1 has been developed through the diastereoselective addition of methylmagnesium bromide or methyllithium to an intermediate tert-butylsulfinimide.

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