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New and efficient routes for the synthesis of murrayaquinone A and murrayanine

✍ Scribed by Shrikar M. Bhosale; Aadil A. Momin; Radhika S. Kusurkar

Book ID
116909550
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
322 KB
Volume
68
Category
Article
ISSN
0040-4020

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A new route to the synthesis of pyrazole and pyrimidine C-nucleosides, involving as the key step a metal catalysed reaction of [3-D-ribofuranosyl ketoesters with alkyl cyanoformates, is described. 2,3,5-Tri-O-benzoyl-13-D-ribofuranosyl cyanide (1) reacts with Β’t-bromoesters, in the presence of zinc