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New 9,10-seco-steroids from 11β-hydroxy-8β,9-epoxy-derivatives

✍ Scribed by Klaus Annen; Helmut Hofmeister; Henry Laurent; Arne Seeger; Rudolf Wiechert

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
229 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of readily available IIR-hydroxy-8B,9-epoxy-steroids with hydrogen fluoride-pyridine gave the corresponding 9.10-seco-derivatives in good yields. Ring cleavages between C-9 and C-IO of steroids by micro-organisms 1) or photo-2)H.H. Inhoffen, Angew. Chem. ;z, 875 (1960).

3)(a) D.

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