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Spectroscopic analysis of 3β-acetoxy-8-hydroxy-8,11-epoxy-8,9-seco-6,11-cyclolanostane-7,9-dione

✍ Scribed by Fred Y. Fujiwara; Vera G. Rehder; Anita J. Marsaioli


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
423 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Spectroscopic analysis of a lanostane derivative, which was synthesized with a view to its application as an intermediate in chiral building block syntheses, is presented together with the conformational analysis of a secolanostane‐7‐8‐9,11‐tetraone.


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✍ Tomasz Janosik; Jan Bergman; Ivan Romero; Birgitta Stensland; Claes Stålhandske; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 300 KB 👁 1 views

7,8]tetrathiacyclododecino [4,3-b:5,6-bЈ:10,9-bЈЈ:11,12-bЈЈЈ]tetraindoles 9a and 9b have been isolated in good yields, and the existence of a third conformer 9c in solution was demonstrated by mass spectrometry and 1 H NMR spectroscopy. The interconversions of the tetraindoles 9a-c have also been st