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New 1,2,3-triazole ligands through click reactions and their palladium and platinum complexes

✍ Scribed by Schweinfurth, David; Pattacini, Roberto; Strobel, Sabine; Sarkar, Biprajit


Book ID
111926761
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
226 KB
Volume
42
Category
Article
ISSN
1477-9226

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The reaction of 1,2-diamines la-c with Ph3PBr2 in the presence of triethylamine gives rise to the corresponding diphosphonium salts 2a-c in good yields. Treatment of these salts with NaH at room temperature in CH,Cl, affords the diiminophosphoranes 3a-c in near quantitative yields. Derivatives 3a,b