Neutron spectroscopic studies of the adsorption and decomposition of C2H2 and C2H4 on raney nickel
β Scribed by R.D. Kelley; R.R. Cavanagh; J.J. Rush; T.E. Madey
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 55 KB
- Volume
- 155
- Category
- Article
- ISSN
- 0167-2584
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.
New high-level quantum chemical calculations have been undertaken to understand the rates and mechanisms of the reactive and associative channels for the reactants C2H2(+) + H2. The reactive channel, which produces C2H3(+) + H, has been shown to be slightly endothermic, confirming earlier calculatio