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Neutral or cationic (μ-methylene)bisylide digoldIII complexes

✍ Scribed by Manuel Bardají; M.Concepción Gimeno; Josefina Jiménez; Antonio Laguna; Mariano Laguna; Peter G. Jones


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
569 KB
Volume
441
Category
Article
ISSN
0022-328X

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Neutral and Cationic Hexanuclear Rhenium
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1±5 were characterised by X-ray crystal structure analysis. A di-substitution reaction occurs on the {Re 6 S i 6 Cl i 2 } 4+ cluster core, where the two inner l 3 -chloro ligands Cl i are substituted by X (X = As, P, NH, O, S) and all six terminal chloro ligands Cl a are exchanged by terminal PPr 3