✦ LIBER ✦
Neutral and Cationic Hexanuclear Rhenium Phosphine Clusters with μ3-(Phosphido-Chalcogenido), μ3-(Arsenido-Chalcogenido), and μ3-(Imido or Oxo-Chalcogenido) Hetero Ligand Shells
✍ Scribed by Andrea Decker; Falk Simon; Kamal Boubekeur; Dieter Fenske; Patrick Batail
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- German
- Weight
- 107 KB
- Volume
- 626
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
1±5 were characterised by X-ray crystal structure analysis. A di-substitution reaction occurs on the {Re 6 S i 6 Cl i 2 } 4+ cluster core, where the two inner l 3 -chloro ligands Cl i are substituted by X (X = As, P, NH, O, S) and all six terminal chloro ligands Cl a are exchanged by terminal PPr 3 -ligands.