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Neutral lipids of the fungus Zoophthora (Erynia) ovispora (NOWAKOWSKI) BATKO

✍ Scribed by M. J. Urbańczyk; Prof. Dr. A. Zabźza; Z. Cichacz; G. Cimino; Dr. J. Szafranek


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
389 KB
Volume
32
Category
Article
ISSN
0233-111X

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✦ Synopsis


The main components of the neutral lipid fractions, isolated from Zoophthora (Erjmia) ovispora, were determined. Triglycerides constitute 56% of total lipids. among them dilaurinostearate glyceride constitutes 43.3%. The major fatty acid -lauric acid (32.3%) is related mainly to tri-and diglycerides. The level of stearic acid is slightly lower (29.8%) but distinctly predominates in free acid fraction. Diglycerides and steroids were present in smaller amounts -1.2% and 4.8%, respectively. Cholesterol exceeds considerably ergosterol.


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Epoxidation of double bond was the main reaction performed by Zoophthora (Erynia) ovispora on methyl and ethyl a-campholenyl ketones 1 and 6. Apart from epoxides 2, 3, 7, and 8, some other products were isolated, with additional oxygen function in a-position to the double bond (9 and 10). The presen