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Microbial transformation of isoprenoid systems by means of Zoophthora (Erynia) ovispora (NOWAKOWSKI) BATKO

✍ Scribed by Jerzy M. Urbańczyk; Jadwiga Sołoducho; Prof. Dr. Andrzej Zabźa; Guido Sodano; Alfonso Grassi

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 450 KB
Volume: 33
Category: Article
ISSN: 0233-111X
DOI: 10.1002/jobm.3620330212

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✦ Synopsis

Epoxidation of double bond was the main reaction performed by Zoophthora (Erynia) ovispora on methyl and ethyl a-campholenyl ketones 1 and 6. Apart from epoxides 2, 3, 7, and 8, some other products were isolated, with additional oxygen function in a-position to the double bond (9 and 10). The presence of the BAEYER-VILLIGER reaction product (4) and diketone 11 is also postulated.

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