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Neutral and Cationic Aluminum Complexes Supported by Sterically Bulky Amidinate Ligands

✍ Scribed by Schmidt, Joseph A. R.; Arnold, John

Book ID: 121499407
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 104 KB
Volume: 21
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om0201011

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## Abstract The reactions of anhydrous LnCl~3~ (Ln = Y, Nd, Sm, Lu) with two equiv. of sodium __N__,__N′__‐dicyclohexyl‐__N′′__‐bis(trimethylsilyl)guanidinate Na[(Me~3~Si)~2~NC(NCy)~2~], obtained from Na[N(SiMe~3~)~2~] and the 1,3‐dicyclohexyl‐substituted carbodiimide CyN=C=NCy in THF, yield the mo