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Synthesis, Characterization, and Reaction of Aluminum Halide Amides Supported by a Bulky β-Diketiminato Ligand

✍ Scribed by Yang, Ying; Schulz, Thomas; John, Michael; Ringe, Arne; Roesky, Herbert W.; Stalke, Dietmar; Magull, Jörg; Ye, Hongqi

Book ID
126792552
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
307 KB
Volume
47
Category
Article
ISSN
0020-1669

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Reaction of trialkylaluminum Al 2 R 6 (R = Me, Et) with 2,2'methylenebis(6-tert-butyl-4-methylphenol) (mbmpH 2 ) gives the dimeric mono(alkyl) complex [Al(mbmp)R] 2 with bridging oxygen atoms. Reaction of [Al(mbmp)R] 2 with one equiv. of 2-propanol results in the formation of the dimeric isopropoxid