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Neue Wege zu Organogalliumhalogeniden

✍ Scribed by Schmidbaur, Hubert ;Findeiss, Wolfgang


Publisher
Wiley (John Wiley & Sons)
Year
1966
Tongue
English
Weight
535 KB
Volume
99
Category
Article
ISSN
0009-2940

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## New Pathways to Precursors of Pentalene Pentalene dimers 2 and 3 are easily available in moderate yields by CuCI,-induced oxidative coupling of dilithium-pentalenediide (5) (Scheme f). On the other hand, NBS bromination of 1,5-dihydropentaIene (4) or of 1.2-dihydropentalene (8) gives unstable 1