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Neither Electron-Precise nor in Accordance with Wade–Mingos Rules: The Ternary Cluster Anion [Ni2Sn7Bi5]3−

✍ Scribed by Felicitas Lips; Prof. Dr. Stefanie Dehnen

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
501 KB
Volume
50
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Neither Electron-Pr
ChemInform Abstract: Neither Electron-Precise nor in Accordance with Wade—Mingos Rules: The Ternary Cluster Anion [Ni2Sn7Bi5]3-.
✍ Felicitas Lips; Stefanie Dehnen 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 20 KB 👁 1 views

Neither Electron-Precise nor in Accordance with Wade-Mingos Rules: The Ternary Cluster Anion [Ni2Sn7Bi5] 3- •en and Ni(cod)2 in en (room temperature, 3 h) followed by toluene layering (2 d, 15% yield). The compound crystallizes in the monoclinic space group Cc with Z = 4 (single crystal XRD). The [