Neighbouring hydroxy-group participation in the opening of epoxides by nucleophiles
β Scribed by Barton, Derek H. R.; Houminer, Yoram
- Book ID
- 118269544
- Publisher
- The Royal Society of Chemistry
- Year
- 1973
- Tongue
- English
- Weight
- 165 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-4936
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π SIMILAR VOLUMES
## Abstract To demonstrate the neighbouringβgroup participation of the 2βbenzyloxy group in the glycosidation of phenols and of strongly acidic alcohols by the diazirine 1, we examined the glycosidation of 4βnitrophenol, 4βmethoxyphenol, (CF~3~)~2~CHOH, MeOH, and iβPrOH by the diazirine 11, derived
With a rlew to syntheslsing trarrs lactones of the desmotroposantonln series, van Tamelen and his associates' studied the Interactions of the anions generated from diethyl malonate and dlethyl methylmalonate with the epoxlde(T) in refluxing ethanolic solution. The lactonic products thus isolated wer