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Influence of solvents and effect of the peri-methyl group in nucleophilic opening-up of epoxides

✍ Scribed by Amareshwar Chatterjee; Dilip Banerjee

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
273 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

With a rlew to syntheslsing trarrs lactones of the desmotroposantonln series, van Tamelen and his associates' studied the Interactions of the anions generated from diethyl malonate and dlethyl methylmalonate with the epoxlde(T) in refluxing ethanolic solution. The lactonic products thus isolated were characterlsed as ('ITT). The exclusive formation of these undesired lactones was

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