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Neighboring-group participation in organic redox reactions: effect of tertiary amine and pyridine groups on the kinetics and mechanism of thioether-sulfoxide interconversions

✍ Scribed by Doi, Joyce Takahashi; Musker, W. Kenneth; DeLeeuw, David L.; Hirschon, Albert S.

Book ID: 127261651
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 673 KB
Volume: 46
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00320a002

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## Abstract Rate constants are reported for the reactions of a series of 1‐chloro‐, 1‐fluoro‐ and 1‐phenoxy‐nitrobenzenes activated by CF~3~ or CN groups or by ring‐nitrogen with __n__‐butylamine, pyrrolidine or piperidine in acetonitrile. The results are compared with results reported previously f