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Anchimerically assisted redox reactions. 7. A comparison of the effects of neighboring primary, secondary, and tertiary amine groups on the kinetics and mechanism of thioether oxidation by aqueous iodine

✍ Scribed by DeLeeuw, David L.; Goodrow, Marvin H.; Olmstead, Marilyn M.; Musker, W. Kenneth; Doi, Joyce T.

Book ID: 126809501
Publisher: American Chemical Society
Year: 1983
Tongue: English
Weight: 520 KB
Volume: 48
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00162a015

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## Sumnary* The rate law for the aqueous I oxidation of 5-amino-1-thiacyclooctane has been determined and compared with 5-hydroxy-1-tglacyclooctane The crystal structures of the 9-azaand 9-oxa-1-thlonlablcyclo[3.3.l]nonanes formed on oxidative cyclization are compared We recently reported the fir