Negative longitudinal expansion and the amplitude of longitudinal vibrations in poly(ethylene) crystals
β Scribed by A. I. Slutsker; V. L. Gilyarov; G. Dadobaev; L. A. Laius; I. V. Gofman; Yu. I. Polikarpov
- Book ID
- 118724998
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 105 KB
- Volume
- 44
- Category
- Article
- ISSN
- 1063-7834
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π SIMILAR VOLUMES
Raman longitudinal acoustic mode (LAM) spectra have been obtained during isothermal crystallization from the melt at various temperatures of a poly(ethylene oxide) (PEO) fraction of molecular weight about 3000 and an a,v-methoxylated fraction (MPEO) derived from it. For both fractions, we find that
## Abstract The chain modulus of poly(ethylene oxide) is determined by the Raman longitudinal acoustic mode method with the aid of a normal coordinate analysis and found to be 1.3 Γ 10^11^ dyn/cm^2^. Our normal mode calculations provide a clear basis for explaining the discrepancy between chain mod