Near-Infrared Diode Laser Spectroscopy of the CCO Radical: Molecular Constants for the X̃3Σ−(010) State

✍ Scribed by N. Ohashi; R. Kiryu; S. Okino; M. Fujitake

• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 249 KB
• Volume: 157
• Category: Article
• ISSN: 0022-2852
• DOI: 10.1006/jmsp.1993.1004

✦ Synopsis

Vib-rotational energy differences between the (\dot{X}(010)^{3} \Pi(b)) and (\dot{X}(000)^{3} \Sigma^{-})states, and purerotational energy differences in the (\bar{X}(010)^{3} \Pi(b)) state of the CCO radical, were obtained from near-infrared absorption spectral data of the (\tilde{A}(010)^{3} \Sigma^{{ }^{-1}}-\hat{X}(000)^{3} \Sigma^{-} . \tilde{A}(010)^{3} \Sigma^{(-)}-\tilde{X}(010)^{3}) II (b), and (\hat{A}(010)^{3} \Sigma^{1+1}-\dot{X}(010)^{3} I I(b)) bands. These energy differences were analyzed to determine molecular constants for the (\hat{X}(010)) II (b) state in detail. Gi 1993 Academic Press. Inc.