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Near-Infrared Diode Laser Spectroscopy of FeC in the 0.8-μm Region: A Simultaneous Analysis of the X3Δi and [3.8]1Δ States

✍ Scribed by Masaharu Fujitake; Aki Toba; Masaya Mori; Fuyuki Miyazawa; Nobukimi Ohashi; Kosuke Aiuchi; Kazuhiko Shibuya


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
466 KB
Volume
208
Category
Article
ISSN
0022-2852

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✦ Synopsis


The near-infrared absorption spectra of the FeC radical have been measured by diode laser spectroscopy in the regions from 11 810 to 13 200 cm -1 . Rotationally resolved 28 new vibronic bands of the 56 Fe 12 C major isotopic species were observed as well as two known bands. Five of them were assigned as the v = v = 0-4 sequence bands in the [13.1] 3 4 ← X 3 3 system, six are the v = v = 0-5 sequences in the [13.18] = 3 ← X 3 2 system, and five were assigned as the v = v = 0-4 sequences in the [13.5] = 2 ← X 3 1 system. The X 3 1 state of FeC is reported for the first time but we found that the rotational constant for this state of 56 FeC is very close to that for the X 3 3 state of 54 FeC. Transitions of the 54 FeC minor isotopic species for the two known bands were thus reinvestigated. For the unclassified 11 new bands, the lower states were assigned as the v = 0-3 states in X 3 i . The energy difference between the = 2 and 3 sublevels in the X 3 i state could be determined to be 329.8059 ± 0.0005 cm -1 as a results of the analysis of the two of new bands, [12.32] ← X 3 3 v = 0 and [12.32] ← X 3 2 v = 0 observed near 12 317 cm -1 and 11 987 cm -1 , respectively. Stimulated emission pumping spectra were also recorded near 17 600 cm -1 to examine the low-lying electronic state which had been observed 3460 cm -1 above the X 3 2 state (K. Aiuchi and K. Tsuji and K. Shibuya, Chem. Phys. Lett. 309, 229-233 (1999)), and it was assigned as the [3.8] 1 state arising from the same configuration as that of X 3 i (. . . 3π 4 1δ 3 9σ 1 ). In addition, the v = 0-0 and 1-1 bands of the [16.2] = 3 ← [3.8] 1 system were observed by near-infrared diode laser spectroscopy. The lower state combination differences were calculated for the possible sets of the energy levels in the X 3 i and [3.8] 1 states with v = 0-5 by using the present result and the other spectroscopic data reported. A simultaneous analysis was carried out by using the combination differences to determine the molecular constants for the X 3 i and [3.8] 1 states as well as the off-diagonal spin-orbit interaction terms. The [13.18] = 3 state and the [13.5] = 2 state were concluded to be other two spin sublevels for the [13.1] 3 4 state and the [16.2] = 3 state was assigned as an isoconfigurational 1 state.


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✍ Hisashi Abe; Yasunori Kawamoto; Masaharu Fujitake; Nobukimi Ohashi; Takamasa Mom 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 468 KB

The A ˜(020)k 3 P-X ˜3S 0 (000) and A ˜3P i (001) -X ˜3S 0 (000) bands of the CCO radical have been investigated by laser spectroscopy with two types of tunable laser system. An analysis was made simultaneously for both the bands to establish line assignments and determine molecular constants for bo