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Ne matrix spectra of the sym-C6Br3F3+ radical cation

✍ Scribed by V.E. Bondybey; T.J. Sears; Terry A. Miller; C. Vaughn; J.H. English; R.S. Shiley


Book ID
103663958
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
710 KB
Volume
61
Category
Article
ISSN
0301-0104

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The reactions (2) (3) have been studied competitively in the vapor phase over the range of 52-204Β°C. The i-C3F7 radicals were generated by means of the reaction It was found that log kz/k3 = (0.55 f 0.07) + (10,870 f 560)/0 where 0 = 2.303RT J/mol. Absolute Arrhenius parameters are derived for the