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NBu4BH4 reduction of 2-cyclohexenones

✍ Scribed by Esther D'Incan; Andre Loupy

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 163 KB
Volume: 40
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)92246-1

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✦ Synopsis

Various studies, including conductivity, surface tension, compressibility, emf-measurement, vapour phase osmometry, solubility and density, have been performed on [PNP]'-halides in water and methanol. It is concluded that these salts are very well dissociated in methanol while in water, [PNP]+Cl-, the most soluble salt, appears to have a critical micelle concentration, 'cmc-value', at -0.005 mol 1-l . References 1 [ PNP]+ designs the bis(triphenylphosphine)iminium cation, [ (PhaP)zN]+.

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