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NaZnPO 4 ·H 2 O, an Open-Framework Sodium Zincophosphate with a New Chiral Tetrahedral Framework Topology

✍ Scribed by Harrison, William T. A.; Gier, Thurman E.; Stucky, Galen D.; Broach, Robert W.; Bedard, Robert A.


Book ID
120418586
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
332 KB
Volume
8
Category
Article
ISSN
0897-4756

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Crystals of NaZn(H2O)2[BP2O8].H2O were grown under mild hydrothermal conditions at 170 degrees C. The crystal structure (solved by X-ray single-crystal methods: hexagonal, P6(1)22 (no. 178), a = 946.2(2), c= 1583.5(1) pm, V= 1227.8(4).10(6) pm3, Z = 6) exhibits a chiral octahedral-tetrahedral framew