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ChemInform Abstract: Fe(H2O) 2BP2O8×H2O, a First Zeotype Ferriborophosphate with Chiral Tetrahedral Framework Topology.

✍ Scribed by Aysen Yilmaz; Xianhui Bu; Meral Kizilyalli; Galen D. Stucky

Publisher
John Wiley and Sons
Year
2001
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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Crystals of NaZn(H2O)2[BP2O8].H2O were grown under mild hydrothermal conditions at 170 degrees C. The crystal structure (solved by X-ray single-crystal methods: hexagonal, P6(1)22 (no. 178), a = 946.2(2), c= 1583.5(1) pm, V= 1227.8(4).10(6) pm3, Z = 6) exhibits a chiral octahedral-tetrahedral framew