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ChemInform Abstract: NaZn(H2O)2 [BP2O8]×H2O: A Novel Open-Framework Borophosphate and Its Reversible Dehydration to Microporous Sodium Zincoborophosphate Na[ZnBP2O8]×H2O with CZP Topology.

✍ Scribed by Insan Boy; Frank Stowasser; Gerd Schaefer; Ruediger Kniep

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
33
Category
Article
ISSN
0931-7597

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NaZn(H2O)2[BP2O8]⋅H2O: A Novel Open-Fram
NaZn(H2O)2[BP2O8]⋅H2O: A Novel Open-Framework Borophosphate and its Reversible Dehydration to Microporous Sodium Zincoborophosphate Na[ZnBP2O8]⋅H2O with CZP Topology
✍ Insan Boy; Frank Stowasser; Gerd Schäfer; Rüdiger Kniep 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 1 views

Crystals of NaZn(H2O)2[BP2O8].H2O were grown under mild hydrothermal conditions at 170 degrees C. The crystal structure (solved by X-ray single-crystal methods: hexagonal, P6(1)22 (no. 178), a = 946.2(2), c= 1583.5(1) pm, V= 1227.8(4).10(6) pm3, Z = 6) exhibits a chiral octahedral-tetrahedral framew