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Nature of the resonant states of NO−

✍ Scribed by H. Lefebvre-Brion

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
266 KB
Volume
19
Category
Article
ISSN
0009-2614

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✦ Synopsis

The stabilization method of' Taylor has been used to cnlculate the nature of the states of NO-corresponding to the lowest resonances observed recently by Sanchc and Schulz. It is conr'imled that they consist of two Rydberg electrons in the core of the X 'Z+ frotmd state of the ion. The proposed assignments are the (Rsu)~~C+, (Rso; (Rpn) 3n, (Rso) (Rpu) 3r+ states. The fourth resonance is attribured to an (Rpn) 2 3E-state. The Rydberg or- bitals of these states of the negative ion are more diffuse than the corresponding ones of the neutral molecule.

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