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Nature of the promoting action of hexene-1 during copolymerization with ethylene on TiCl4/MgCl2

✍ Scribed by S.S. Ivanchev; A.V. Kryzhanovskii; I.I. Gapon; Ye.L. Ponomareva

Book ID
116049527
Publisher
Elsevier Science
Year
1990
Weight
308 KB
Volume
32
Category
Article
ISSN
0032-3950

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MgCl 2 /THF/TiCl 4 (TT-0) were thermally pretreated at 80ЊC for 5 min (TT-1) and 60 min (TT-2), and at 108ЊC for 5 min (TT-3) and 60 min (TT-4). These thermally pretreated catalysts showed comonomer enhancement effects in the ethylene-1-hexene copolymerization, while TT-0 catalyst did not. Comonomer