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Copolymerization of ethylene and 1-hexene with TiCl4/MgCl2catalysts modified by 2,6-diisopropylphenol

✍ Scribed by Sheng-jie Xia,Zhi-sheng Fu,Xiao-yan Liu…

Book ID
126348182
Publisher
Institute of Chemistry Chinese Academy of Sciences
Year
2012
Tongue
English
Weight
297 KB
Volume
31
Category
Article
ISSN
0256-7679

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Copolymerization of ethylene–1-Hexene over a thermally pretreated MgCl2/THF/TiCl4 bimetallic catalyst
✍ Young Soo Ko; Taek Kyu Han; Je Woo Park; Seong Ihl Woo 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

MgCl 2 /THF/TiCl 4 (TT-0) were thermally pretreated at 80ЊC for 5 min (TT-1) and 60 min (TT-2), and at 108ЊC for 5 min (TT-3) and 60 min (TT-4). These thermally pretreated catalysts showed comonomer enhancement effects in the ethylene-1-hexene copolymerization, while TT-0 catalyst did not. Comonomer