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Nature of the 2-bicyclo[2.1.1]hexyl cation

โœ Scribed by Seybold, Gunther.; Vogel, Pierre.; Saunders, Martin.; Wiberg, Kenneth B.


Book ID
121854674
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
375 KB
Volume
95
Category
Article
ISSN
0002-7863

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A recent report (1) describing the nature of the 2-bicyclo[3.1.0]hexyl cation formed in the solvolysis of epimeric 2-chlorobicyclo[3.1.0]hexanes prompts us to report our work on this system which provides an explanation for the small difference in rate between endo-and exo-isomers. Endo-(Ib) and ex