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A rigid cyclopropylcarbinyl system. The 2-bicyclo[3.1.O]hexyl cation

โœ Scribed by George H. Schmid; Allister Brown

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
176 KB
Volume
9
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A recent report (1) describing the nature of the 2-bicyclo[3.1.0]hexyl cation formed in the solvolysis of epimeric 2-chlorobicyclo[3.1.0]hexanes prompts us to report our work on this system which provides an explanation for the small difference in rate between endo-and exo-isomers.

Endo-(Ib) and exo-bicyclo[3.l.O]hexan-2-01 (IIb) were prepared by the

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