Methyl substituent effects on cyclopropylcarbinyl-cyclopropylcarbinyl cation rearrangements in the 2-bicyclo[4.1.0]heptyl system

✍ Scribed by Edwin C. Friedrich; J.Diane Cooper Jassawalla

• Publisher: Elsevier Science
• Year: 1978
• Tongue: French
• Weight: 228 KB
• Volume: 19
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)85423-x

✦ Synopsis

We recently reported' a study of cyclopropylcarbinyl-cyclopropylcarbinyl cation rear-rangements2 in perchloric acid catalyzed acetolyses3 of the 2-deuterio-endo-and exo-2-bicyclo[n.l.0lalkanols (n = 3 to 6). In none of the systems examined was the amount of