Spectrophotometric studies show that phenosafranin (PSF), a cationic phenazine dye forms 1:1 molecular complexes with phosphatidylcholine (PC), lysoPC and Ca-salt of phosphorylcholine chloride 0aCC) in sonicated aqueous dispersion and the site of interaction in PC has been identified. The same syste
Nature of interaction of phospholipid liposome with iodine
โ Scribed by Ira Chatterjee; Papiya Nandy; Benoy B. Bhowmik
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 450 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0009-3084
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โฆ Synopsis
The sonicated dispersion of phospholipids in water is found to form a 1:1 molecular complex with iodine when the concentration of phospholipid is above the critical value (1.6ร 10-5moldm-3). From thermodynamic as well as spectrophotometric studies, the electron donating property of several phospbolipids [phosphatidylethanolamine (PE), lyso PE (LPE), phosphatidylcholine (PC: earlier result), lyso PC (LPC) and sphingomyelin (SM)] have been compared. The kinetics of interaction in the case of Pc-iodine complex have also been studied. Results iadicate that the mode of lipid organization plays a significant role in the complex formation. The nature of this interaction as well as the site of interaction in phospholipids are identified.
๐ SIMILAR VOLUMES
The electron donor acceptor complexes of iodine with phospholipids such as phosphatidylethanolamine (PE), lysophosphatidylcholine ILPC) and sphingomyelin (SM) have been studied spectrophotometrically in cyclohexane solution as well as in solid film. From the results, the electron donating properties
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