Nature of Aliphatic C-Nitroso Compounds. I. Study of the Rate of Dissociation of the Aliphatic C-Nitroso Dimer in Various Solvents
β Scribed by Schwartz, Joseph R.
- Book ID
- 127310081
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 383 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
A review of the chemical literature reveals a number of addition reactions to the nitroso functional group which appear analogous in many respects to those observed for carbonyl compounds. 1 It is also recognized that nitroso compounds are excellent acceptors of electrons from anionic species to yi
C-nitroso compounds are of considerable interest in chemistry because of dimerization and cis-trans isomerization of the dimer. The climer formation has rf~. 26 The two kinds of exchange processes do not interfere and can be treated independently by the NMR line-shape method. Currently we carry out