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Natural abundance 17O NMR spectra of some sulphinylimines and isocyanates

✍ Scribed by C. O. Della Vedova; H. Duddeck; H.-W. Praas

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
190 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^17^O chemical shifts of nine sulphinylimines and isocyanates are reported and discussed in terms of electronic and mesomeric effects. Unusually large values were found for the sulphinylimines. The differences in acyl fluorides compared with acyl chlorides are rationalized on the basis of a mesomeric form, implying an increase of the carbonyl bond order.

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