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Cover of Natun Bouthan

Natun Bouthan

โœ Scribed by Ranjan Bandyopadhyay


Book ID
111894302
Publisher
Deep Prakashan
Year
2020
Tongue
Bengali
Weight
159 KB
Category
Fiction
ISBN
8185800421

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fl-Ketooxime [RC(O)C(NOH)R] (R = Me or Ph) ligands (HL) react with [Ru(PPh3)3C12] in refluxing EtOH to yield [Ru(PPh3)2(L)2'] complexes. For R=Me, one isomer was obtained, while two isomers were isolated when R = Ph, due to a bulk effect. The complexes are diamagnetic and absorb intensely in the vis

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Using 1,2-naphthoquinone-1-oxime (HL) as the principal ligand, four mixed-ligand ruthenium oximate complexes -namely [Ru(bipy)2(L)]C104, [Ru(pap)a(L)]-C10 4, [Ru(bipy)(L)2 ] and [Ru(PPh3)2(L)2 ], where bipy = 2,2'-bipyridine and pap = 2-(phenylazo)pyridinehave been synthesized and characterized. In