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Chemistry of ruthenium-picolinates. Synthesis, characterization and cyclic voltammetric studies

โœ Scribed by Natun Ghatak; Joydip Chakravarty; Samaresh Bhattacharya


Book ID
112921113
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1996
Tongue
English
Weight
38 KB
Volume
108
Category
Article
ISSN
0253-4134

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๐Ÿ“œ SIMILAR VOLUMES


Synthesis, characterization and cyclic v
โœ Natun Ghatak; Samaresh Bhattacharya ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Springer ๐ŸŒ English โš– 485 KB

Using 1,2-naphthoquinone-1-oxime (HL) as the principal ligand, four mixed-ligand ruthenium oximate complexes -namely [Ru(bipy)2(L)]C104, [Ru(pap)a(L)]-C10 4, [Ru(bipy)(L)2 ] and [Ru(PPh3)2(L)2 ], where bipy = 2,2'-bipyridine and pap = 2-(phenylazo)pyridinehave been synthesized and characterized. In

Synthesis, characterization and cyclic v
โœ Natun Ghatak; Samaresh Bhattacharya ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Springer ๐ŸŒ English โš– 415 KB

fl-Ketooxime [RC(O)C(NOH)R] (R = Me or Ph) ligands (HL) react with [Ru(PPh3)3C12] in refluxing EtOH to yield [Ru(PPh3)2(L)2'] complexes. For R=Me, one isomer was obtained, while two isomers were isolated when R = Ph, due to a bulk effect. The complexes are diamagnetic and absorb intensely in the vis