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NaOAc-Mediated Selective Deprotection of Aromatic Acetates and Its Application in the Synthesis of Natural Products

✍ Scribed by Narender, T.; Reddy, K. Papi; Madhur, G.

Book ID
120445749
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
366 KB
Volume
39
Category
Article
ISSN
0039-7911

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Selective oxidation of primary silyl eth
Selective oxidation of primary silyl ethers and its application to the synthesis of natural products
✍ A. RodrΓ­guez; M. Nomen; B.W. Spur; J.J. Godfroid πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 250 KB

Primary TMS or TES ethers, in the presence of secondary TMS or TES ethers, are selectively oxidized to the corresponding aldehydes under Swern conditions. A short synthesis of key intermediates towards various natural products has been achieved.