𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Selective oxidation of primary silyl ethers and its application to the synthesis of natural products

✍ Scribed by A. Rodríguez; M. Nomen; B.W. Spur; J.J. Godfroid

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
250 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Primary TMS or TES ethers, in the presence of secondary TMS or TES ethers, are selectively oxidized to the corresponding aldehydes under Swern conditions. A short synthesis of key intermediates towards various natural products has been achieved.

📜 SIMILAR VOLUMES

ChemInform Abstract: Selective Oxidation
ChemInform Abstract: Selective Oxidation of Primary Silyl Ethers and Its Application to the Synthesis of Natural Products.
✍ A. Rodriguez; M. Nomen; B. W. Spur; J. J. Godfroid 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

Selective Oxidation of Primary Silyl Ethers and Its Application to the Synthesis of Natural Products. -The direct oxidation of primary Tms and Tes ethers in the presence of various functional groups including secondary silyl ethers selectively yields the aldehydes (II) as useful intermediates for l